Partition Coefficients
The fluorous character of a molecule can be assessed by its partition coefficient between a perfluorocarbon and a hydrocarbon. In the following table, the data are for perfluoromethylcyclohexane:toluene.
solute | partition coefficient for CF3C6F11:toluene |
octane | 5.4:94.6 |
CH3(CH2)13CH=CH2 | 0.9:99.1 |
C6H6 | 6:94 |
C6F6 | 28.0:72.0 |
C10F22(CH2)3OH | 80.5:19.5 |
C8F20(CH2)3C6H5 | 49.5:50.5 |
C8F20C6H5 | 77.5:22.5 |
Read more about this topic: Fluorous Chemistry