Bromopentacarbonylrhenium(I) is an inorganic compound of rhenium, commonly used for the syntheses of other rhenium complexes.

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Bromopentacarbonylrhenium(I) - Reactions
... Refluxing bromopentacarbonylrhenium(I) in water also provides access to the rhenium tricarbonyl fragment ReBr(CO)5 + 3 H2O → Br + 2 CO This route avoids the formation of the tetraethylammonium bromide byproduct when the tetraethylammonium complex is used ... This is desirable because the tetraethylammonium bromide is often difficult to remove from reaction mixtures ...