When a chemical reaction or formation of a molecular complex or exhibits a linear relationship between enthalpy and entropy, one might observe what is known as an enthalpy-entropy compensation, where the magnitude of change in the Gibbs free energy is less than one might expect.
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... Athel Cornish-Bowden has argued enthalpy-entropy is probably a statistical artifact, which could result in observing a relationship between two variables which ... Criticism of the enthalpy-entropy compensation arises from this strong correlation, which is “too good to be true.” It is believed these plots are a result of looking at the ...
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“Many old people receive pensions for no other reason, it seems to me, but as a compensation for having lived a long time ago.”
—Henry David Thoreau (18171862)