Rate Equation - Equilibrium Reactions or Opposed Reactions

Equilibrium Reactions or Opposed Reactions

A pair of forward and reverse reactions may define an equilibrium process. For example, A and B react into X and Y and vice versa (s, t, u, and v are the stoichiometric coefficients):

The reaction rate expression for the above reactions (assuming each one is elementary) can be expressed as:

where: k1 is the rate coefficient for the reaction that consumes A and B; k2 is the rate coefficient for the backwards reaction, which consumes X and Y and produces A and B.

The constants k1 and k2 are related to the equilibrium coefficient for the reaction (K) by the following relationship (set r=0 in balance):

Read more about this topic:  Rate Equation

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