Dynamic NMR Spectroscopy
Indicative of interplay between applications and fundamental science were many studies on stereodynamics conducted at CRD by Jesson, Meakin, and Muetterties. One of the early studies focused on the non-rigidity of SF4, a reagent relevant to the preparation of fluorocarbons. Subsequent studies led to the discovery of the first stereochemically non-rigid octahedal complexes of the type FeH2(PR3)4.
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Other articles related to "nmr, spectroscopy":
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... Carbon satellites are small peaks that can be seen shouldering the main peaks in an NMR spectrum ... These peaks can occur in the NMR spectrum of any NMR active atom (e.g. 19F or 31P NMR) where those atoms adjoin a carbon atom (and where the spectrum is not 13C-decoupled, which is usually the case) ...
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