Ring Strain

In organic chemistry, ring strain is the tendency of a cyclic molecule, such as cyclopropane, to destabilize when its atoms are in non-favorable high energy spatial orientations. Non-cyclic molecules do not exhibit ring strain because their terminal (end) atoms are not connected to force a particular type of spatial orientation.

Ring strain results from a combination of angle strain, conformational strain or Pitzer strain, and transannular strain or van der Waals strain.

Read more about Ring StrainExamples, Organic Synthesis, See Also

Other articles related to "rings, ring strain, ring, strain":

Carbon Ring
... Carbon rings are rings of carbon atoms ... Rings of five and six carbons are by far the most common, as they allow bond angles close to the ideal angle of 109.5° ... Rings of three and four are possible, but with bond angles of 60° and 90°, they have a larger ring strain and are unstable ...
Ring Strain - See Also
... Strain (chemistry) Angle strain . ...
Benson Group Increment Theory - Limitations - Ring Strain, Intermolecular and Intramolecular Interactions
... However, a small ring such as cyclobutane leads to a substantial failure for the BGIT, because of its strain energy ... A series of correction terms for common ring systems has been developed, with the goal of obtaining accurate △Hf0 values for cyclic system ... Note that these are not identically equal to the accepted strain energies for the parent ring system, although they are quite close ...

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