The **characteristic rotational temperature** (θ_{R} or θ_{rot}) is commonly used in statistical thermodynamics, to simplify the expression of the rotational partition function and the rotational contribution to molecular thermodynamic properties. It has units of temperature and is defined as

,

where B is the rotational constant, and is a molecular moment of inertia. Also h is the Planck constant, c is the speed of light, ħ = h/2π is the reduced Planck constant and *k _{B}* is the Boltzmann constant.

The physical meaning of θ_{R} is as an estimate of the temperature at which thermal energy (of the order of k_{B}T) is comparable to the spacing between rotational energy levels (of the order of hcB). At about this temperature the population of excited rotational levels becomes important. Some typical values are 88 K for H_{2}, 15.2 K for HCl and 0.561 K for CO_{2}.

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