Rotational-vibrational Spectroscopy

Rotational-vibrational Spectroscopy


Rovibrational coupling is a coupled rotational and vibrational excitation of a molecule. It is different from rovibronic coupling, which involves a change in all of electronic, vibrational, and rotational states simultaneously.

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Rotational-vibrational Spectroscopy - Rotational-Vibrational Spectroscopy - Evaluating Spectra
... In spectroscopy, the transitions where are referred to as the P-branch ... Rotational-vibrational spectra will also show some fine structure due to the presence of different isotopes in the spectrum ...