Methyl Acrylate

Methyl acrylate is an organic compound with the formula CH2CHCO2CH3. It is the methyl ester of acrylic acid. It is a colourless liquid with a characteristic acrid odor. It is mainly produced to make acrylate fiber, which is used to weave synthetic carpets. It is also a reagent in the synthesis of various pharmaceutical intermediates.

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1,3-Dipolar Cycloaddition - Regioselectivity
... the cycloaddition of diazomethane to three dipolarophiles methyl acrylate, styrene or methyl cinnamate ... Methyl acrylate and styrene bear the largest LUMO lobe on the terminal olefinic carbon -- this can be easily predicted based on resonance structures ... For the more complex case of methyl cinnamate, the two substituents compete at withdrawing electrons from the alkene ...