Enolates Exhibit

Some articles on enolates, enolates exhibit:

Aldol Reaction - Stereoselectivity - Alpha Stereocenter On The Electrophile
... When enolates attacks aldehydes with an alpha stereocenter, excellent stereocontrol is also possible ... The general observation is that E enolates exhibit Felkin diastereoface selection, while Z enolates exhibit anti-Felkin selectivity ... The general model is presented below Since Z enolates must react through a transition state that contains either a destabilizing syn-pentane interaction or an anti-Felkin rotamer ...

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