**Born–Oppenheimer Approximation**

In quantum chemistry, the computation of the energy and the wavefunction of an average-size molecule is a formidable task that is alleviated by the **Born–Oppenheimer** (**BO**) **approximation**, named after Max Born and J. Robert Oppenheimer. For instance the benzene molecule consists of 12 nuclei and 42 electrons. The time independent Schrödinger equation, which must be solved to obtain the energy and wavefunction of this molecule, is a partial differential eigenvalue equation in 162 variables—the spatial coordinates of *the electrons and the nuclei*. The BO approximation makes it possible to compute the wavefunction in two less complicated consecutive steps. This approximation was proposed in 1927, in the early period of quantum mechanics, by Born and Oppenheimer and is still indispensable in quantum chemistry.

In basic terms, it allows the wavefunction of a molecule to be broken into its electronic and nuclear (vibrational, rotational) components.

In the first step of the BO approximation the *electronic* Schrödinger equation is solved, yielding the wavefunction depending on electrons only. For benzene this wavefunction depends on 126 electronic coordinates. During this solution the nuclei are fixed in a certain configuration, very often the equilibrium configuration. If the effects of the quantum mechanical nuclear motion are to be studied, for instance because a vibrational spectrum is required, this electronic computation must be in nuclear coordinates. In the second step of the BO approximation this function serves as a potential in a Schrödinger equation *containing only the nuclei*—for benzene an equation in 36 variables.

The success of the BO approximation is due to the high ratio between nuclear and electronic masses. The approximation is an important tool of quantum chemistry; without it only the lightest molecule, H_{2}, could be handled, and all computations of molecular wavefunctions for larger molecules make use of it. Even in the cases where the BO approximation breaks down, it is used as a point of departure for the computations.

The electronic energies, constituting the nuclear potential, consist of kinetic energies, interelectronic repulsions and electron–nuclear attractions. In a handwaving manner the nuclear potential is taken to be an averaged electron–nuclear attraction. The BO approximation follows from the inertia of electrons being considered to be negligible in comparison to the atom to which they are bound.

In molecular spectroscopy, because the ratios of the periods of the electronic, vibrational and rotational energies are each related to each other on scales in the order of a thousand, the Born-Openheimer name has also been attached to the approximation where the energy components are treated separately.

The nuclear spin energy is so small that it is normally omitted.

Read more about Born–Oppenheimer Approximation: Short Description, Derivation of The Born–Oppenheimer Approximation

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